NOBLE GASES
Introduction of Noble Gases - These gases are also known as Inert
Gases or rare gases or nobel gases . They were called inert gases
because they are chemically inert.they occur in nature in less quantities hence
were called rare gases. We are also called noble gases because like noble
metals they found in free state and enter into some chemical reaction under
specific codition .
Electronic configuration of noble gase - The outer most shell
of these elements has ns2, np6
electronic configuration except helium because helium has 1s2
electronic configuration . the outer most shell of noble gases is full fill so
they can neither donate nor accept any electron and that’s why zero- valent
they are chemically inert.
Atomic number
|
Element
|
Electronic configuration
|
2
|
He
|
1s2
|
10
|
Ne
|
1s2, 2s2,
2p6
|
18
|
Ar
|
1s2,
2s2, 2p6, 3s2, 3p6
|
36
|
Kr
|
1s2,
2s2, 2p6, 3s2, 3p6, 3d10,
4s2, 4p6
|
54
|
Xe
|
1s2,
2s2, 2p6, 3s2, 3p6, 3d10,
4s2, 4p6, 4d10, 5s2, 5p6
|
86
|
Rn
|
1s2,
2s2,2p6, 3s2,3p6,3d10,
4s2, 4p6,4d10, 4f14, 5s2,
5p6, 5d10, 6s2, 6p6
|
Inertness
causes of Noble Gases
·
Noble
gases have ns2, np6 electronic configuration in their
outer most shell except helium because it’s have 1s2 electronic configuration. Thus they can
neither donate nor accept any electron hence they are chemically inert.
·
All
electrons are paired hence electrons are not available for sharing .therefore
they are unable to form covalent compounds.
·
Noble
gses are unable to expand their valency shell. Thus the formation of
compounds is not possible.
·
Due
to low electron affinity they can not accept electrons and hence are unable to
form compounds.
Physical
properties of noble gases-
·
Noble
gases are colourless, odourless, and tasteless.
·
Noble
gases are monoatomoc.
·
They
are slighty soluble in water.
·
Noble
gases can be liquefiedat suitable temperatures.
·
Their
atomic radii, density, melting point, boiling
points increase with increase in atomic number.
·
Their
ionisation potential gradually decreases at the atomic number increases.
Chemical
properties of noble gases-
Noble gases
have high ionisation potential and negligible electron affinity,therefor they
can neither donate nor accept electrons
they are chemically inert in the normal state.
However the noble gases may form
compounds under the following conditions .
1. Compounds formed under excited
condition.
2. Compounds formed through
co-ordination.
3. Compounds formed through dipole
induced dipole attraction.
4. Compounds formed by physical
trapping.
Compounds of xenon- XeF2 , XeF4 , XeF6 , XeOF2
, XeOF4 , XeO2F2 , XeO3 , XeO4
Compounds of krypton- KrF2 , KrF4
Compounds of radon- RaF4
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